Use MPEG Streamclip to open one of the H264 files, then "save as" an MP4 with another name. Drop that file into iTunes. Go back to your AppleTV. Select the AppleTV as the source, then select your iTunes Library as the source (to refresh). See if the file shows up. (Note that "save as" is not "export".)
Alternatively, use MPEG Streamclip to open one of the H264 files, set a 20 second clip using the in/out commands, and "save as" to another name. Post the file where I can download it and check it out.
Another alternative: Same as above but use the "Export as mp4" command with that short clip. Drop that into iTunes. Repeat the "refresh" stuff and see if it appears.
PM me if you want to send me a short clip I can examine. I have found a few podcasts that will sync but will not show up for streaming. What are you using to rip the DVDs to H264?
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